The Hexachlorocerate(III) Anion: A Potent, Benchtop Stable, and Readily Available Ultraviolet A Photosensitizer for Aryl Chlorides | Zendy

Haolin Yin | Zendy; Yi Jin | Zendy; Jerald E. Hertzog | Zendy; Kimberly C. Mullane | Zendy; Patrick J. Carroll | Zendy; Brian C. Manor | Zendy; Jessica M. Anna | Zendy; Eric J. Schelter | Zendy

Open Access

The Hexachlorocerate(III) Anion: A Potent, Benchtop Stable, and Readily Available Ultraviolet A Photosensitizer for Aryl Chlorides

Author(s) -

Haolin Yin,

Yi Jin,

Jerald E. Hertzog,

Kimberly C. Mullane,

Patrick J. Carroll,

Brian C. Manor,

Jessica M. Anna,

Eric J. Schelter

Publication year - 2016

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/jacs.6b05712

Subject(s) - chemistry , photosensitizer , aryl , ultraviolet , ion , combinatorial chemistry , photochemistry , organic chemistry , alkyl , physics , quantum mechanics

The hexachlorocerate(III) anion, [Ce III Cl 6 ] 3- , was found to be a potent photoreductant in acetonitrile solution with an estimated excited-state reduction potential of -3.45 V versus Cp 2 Fe 0/+ . Despite a short lifetime of 22.1(1) ns, the anion exhibited a photoluminescence quantum yield of 0.61(4) and fast quenching kinetics toward organohalogens allowing for its application in the photocatalytic reduction of aryl chloride substrates.

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