Poly(isophthalic acid)(ethylene oxide) as a Macromolecular Modulator for Metal–Organic Polyhedra | Zendy

TengHao Chen | Zendy; Le Wang | Zendy; Jonathan V. Trueblood | Zendy; Vicki H. Grassian | Zendy; Seth M. Cohen | Zendy

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Poly(isophthalic acid)(ethylene oxide) as a Macromolecular Modulator for Metal–Organic Polyhedra

Author(s) -

TengHao Chen,

Le Wang,

Jonathan V. Trueblood,

Vicki H. Grassian,

Seth M. Cohen

Publication year - 2016

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/jacs.6b04971

Subject(s) - isophthalic acid , chemistry , ethylene oxide , polymer , metal , oxide , macromolecule , ethylene , ligand (biochemistry) , organic compound , poly ethylene , polymer chemistry , chemical engineering , inorganic chemistry , organic chemistry , polyester , catalysis , copolymer , biochemistry , receptor , engineering , terephthalic acid

A new strategy was developed by using a polymer ligand, poly(isophthalic acid)(ethylene oxide), to modulate the growth of metal-organic polyhedra (MOP) crystals. This macromolecular modulator can effectively control the crystal habit of several different Cu24L24 (L = isophthalic acid derivatives) MOPs. The polymer also directed the formation of MOP structures under reaction conditions that only produce metal-organic frameworks in the absence of modulator. Moreover, the polymer also enabled the deposition of MOP crystals on glass surfaces. This macromolecular modulator strategy provides an innovative approach to control the morphology and assembly of MOP particles.

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