Open AccessAtomic Structure of Self-Assembled Monolayer of Thiolates on a Tetragonal Au92 Nanocrystal
Author(s) -
Chenjie Zeng,
Chong Liu,
Yuxiang Chen,
Nathaniel L. Rosi,
Rongchao Jin
Publication year - 2016
Publication title -
journal of the american chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 7.115
H-Index - 612
eISSN - 1520-5126
pISSN - 0002-7863
DOI - 10.1021/jacs.6b04835
Subject(s) - nanocrystal , chemistry , overlayer , tetragonal crystal system , monolayer , crystallography , self assembly , nanotechnology , chemical physics , crystal structure , materials science , biochemistry , organic chemistry
Unveiling the ligand binding mode on the crystalline surfaces is important for deciphering the long-standing structural enigma in self-assembled monolayers (SAMs). Here, the binding and patterning structures of thiolates (SR) on the Au(100) crystalline facet are revealed on the basis of the atomic structure of a highly regular, single crystalline Au92(SR)44 nanocrystal. The six exposed facets of this tetragonal nanocrystal give rise to six pieces of "nanoSAMs". We found that thiolates bind to the planar (100) facets of the nanocrystal via a simple bridge-like mode and are assembled into an overlayer with c(2 × 2) symmetry. The Au-S binding mode and translational symmetry in the kernel and on the surface of the Au92 nanocrystal can be generalized infinitely to construct the bulk two-dimensional SAMs and various tetragonal nanocrystals.