Open AccessMechanistic Studies of a Skatole-Forming Glycyl Radical Enzyme Suggest Reaction Initiation via Hydrogen Atom Transfer
Author(s) -
Beverly Fu,
Azadeh Nazemi,
Benjamin J. Levin,
Zhongyue Yang,
Heather J. Kulik,
Emily P. Balskus
Publication year - 2022
Publication title -
journal of the american chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 7.115
H-Index - 612
eISSN - 1520-5126
pISSN - 0002-7863
DOI - 10.1021/jacs.1c13580
Subject(s) - decarboxylation , chemistry , oxidative decarboxylation , hydrogen atom abstraction , kinetic isotope effect , enzyme , radical , hydrogen atom , stereochemistry , photochemistry , biochemistry , organic chemistry , catalysis , deuterium , physics , alkyl , quantum mechanics
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