Low-Valent Tungsten Catalysis Enables Site-Selective Isomerization–Hydroboration of Unactivated Alkenes | Zendy

Tanner C. Jankins | Zendy; Raúl MartínMontero | Zendy; Phillippa Cooper | Zendy; Rubén Martı́n | Zendy; Keary M. Engle | Zendy

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Low-Valent Tungsten Catalysis Enables Site-Selective Isomerization–Hydroboration of Unactivated Alkenes

Author(s) -

Tanner C. Jankins,

Raúl MartínMontero,

Phillippa Cooper,

Rubén Martı́n,

Keary M. Engle

Publication year - 2021

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/jacs.1c07162

Subject(s) - chemistry , hydroboration , isomerization , catalysis , tungsten , photochemistry , combinatorial chemistry , organic chemistry

A tungsten-catalyzed hydroboration of unactivated alkenes at distal C(sp 3 )-H bonds aided by native directing groups is described herein. The method is characterized by its simplicity, exquisite regio- and chemoselectivity, and wide substrate scope, offering a complementary site-selectivity pattern to other metal-catalyzed borylation reactions and chain-walking protocols.

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