PCR-like Cascade Reactions in the Context of an Allosteric Enzyme Mimic | Zendy

Hyo Jae Yoon | Zendy; Chad A. Mirkin | Zendy

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PCR-like Cascade Reactions in the Context of an Allosteric Enzyme Mimic

Author(s) -

Hyo Jae Yoon,

Chad A. Mirkin

Publication year - 2008

Publication title -

journal of the american chemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 7.115

H-Index - 612

eISSN - 1520-5126

pISSN - 0002-7863

DOI - 10.1021/ja804076q

Subject(s) - chemistry , allosteric regulation , cascade , supramolecular chemistry , catalysis , context (archaeology) , cascade reaction , enzyme , enzyme catalysis , combinatorial chemistry , ion , allosteric enzyme , stereochemistry , organic chemistry , chromatography , molecule , paleontology , biology

A supramolecular allosteric catalyst that exhibits a PCR-like cascade reaction is reported. The complex is triggered by a reaction with an acetate ion, which turns on a catalytic cascade that exponentially increases acetate ion concentration through an acyl transfer reaction.

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