Exploration of Chemically Cross-Linked Metal–Organic Frameworks | Zendy

C.A. Allen | Zendy; Seth M. Cohen | Zendy

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Exploration of Chemically Cross-Linked Metal–Organic Frameworks

Author(s) -

C.A. Allen,

Seth M. Cohen

Publication year - 2014

Publication title -

inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 233

eISSN - 1520-510X

pISSN - 0020-1669

DOI - 10.1021/ic500951b

Subject(s) - chemistry , rational design , metal organic framework , crystallinity , monomer , ligand (biochemistry) , lattice (music) , benzene , porosity , metal , crystallography , stereochemistry , organic chemistry , nanotechnology , polymer , biochemistry , materials science , receptor , physics , adsorption , acoustics

A series of geometrically constrained, cross-linked benzene dicarboxylic acid (bdc) derivatives have been synthesized and incorporated into the canonical isoreticular metal-organic framework (IRMOF) lattice. Only certain cross-links, which allow for the proper relative orientation of the bdc subunits, form the desired IRMOF. Design criteria from these cross-linked ligands allowed for the rational design of two oligomeric ligands composed of three bdc monomers tethered together. These oligomeric ligands were also readily incorporated into an IRMOF lattice with a high degree of crystallinity and porosity, providing a new dimension to rational ligand design for metal-organic frameworks.

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