AgNb7O18: An Ergodic Relaxor Ferroelectric
Author(s) -
D. Woodward,
Richard Beanland
Publication year - 2014
Publication title -
inorganic chemistry
Language(s) - Uncategorized
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 233
eISSN - 1520-510X
pISSN - 0020-1669
DOI - 10.1021/ic5007346
Subject(s) - chemistry , ergodic theory , ferroelectricity , relaxor ferroelectric , condensed matter physics , crystallography , pure mathematics , quantum mechanics , dielectric , physics , mathematics
AgNb7O18 is a relaxor ferroelectric with a Burns temperature of ~490 K and an incipient transition to the nonergodic state. The short-range structure is shown by convergent-beam electron diffraction to have the polar space group Im2m, but refinements against powder X-ray diffraction find the long-range structure to have the centrosymmetric space group Immm. Relaxor behavior in AgNb7O18 appears to originate from the partial occupation of large interstices by Ag(+) cations. Both cations and oxygen anions are displaced away from zones where NbO6 octahedra are edge-sharing.
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