Transmetalation of Aqueous Inorganic Clusters: A Useful Route to the Synthesis of Heterometallic Aluminum and Indium Hydroxo—Aquo Clusters | Zendy

Maisha K. KamundeDevonish | Zendy; Milton N. Jackson | Zendy; Zachary L. Mensinger | Zendy; Lev N. Zakharov | Zendy; Darren W. Johnson | Zendy

Open Access

Transmetalation of Aqueous Inorganic Clusters: A Useful Route to the Synthesis of Heterometallic Aluminum and Indium Hydroxo—Aquo Clusters

Author(s) -

Maisha K. KamundeDevonish,

Milton N. Jackson,

Zachary L. Mensinger,

Lev N. Zakharov,

Darren W. Johnson

Publication year - 2014

Publication title -

inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 233

eISSN - 1520-510X

pISSN - 0020-1669

DOI - 10.1021/ic403121r

Subject(s) - chemistry , transmetalation , indium , aqueous solution , aluminium , inorganic chemistry , combinatorial chemistry , catalysis , organic chemistry

[AlxIny(μ3-OH)6(μ-OH)18(H2O)24](NO3)15 hydroxy-aquo clusters (AlxIn13-x) are synthesized through the evaporation of stoichiometrically varied solutions of Al13 and In(NO3)3 using a transmetalation reaction. Several spectroscopic techniques ((1)H NMR, (1)H-diffusion ordered spectroscopy, dynamic light scattering, and Raman) are used to compare AlxIn13-x to its Al13 counterpart. A thin film of aluminum indium oxide was prepared from an Al7In6 cluster ink, showing its utility as a precursor for materials.

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