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An efficient method has been developed for the synthesis of uniquely substituted pyrazolo[1,5- a ]pyridine and pyrido[1,2- b ]indazole derivatives, which involves acetic acid and molecular oxygen promoted cross-dehydrogenative coupling reactions of respective β-ketoesters and β-diketones (like ethyl acetoacetate, ethyl benzoylacetate, methyl propionylacetate, acetylacetone, dimedone, 1,3-cyclohexanedione, and 1,3-cyclopentanedione) with N -amino-2-iminopyridines. The proposed tentative mechanism involves formal acetic acid-promoted oxidative C(sp 3 )-C(sp 2 ) dehydrogenative coupling followed by dehydrative cyclization under a catalyst-free condition within high atom economy processes.

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Synthetic Strategy for Pyrazolo[1,5-a]pyridine and Pyrido[1,2-b]indazole Derivatives through AcOH and O2-Promoted Cross-dehydrogenative Coupling Reactions between 1,3-Dicarbonyl Compounds and N-Amino-2-iminopyridines