
Novel Microwave Absorber of NixMn1–xFe2O4/Carbonized Chaff (x = 0.3, 0.5, and 0.7) Based on Biomass
Author(s) -
Yali Qi,
Pengfei Yin,
Limin Zhang,
Jian Wang,
Xiqi Feng,
Kaiming Wang,
Liang Zhao,
Xiaowei Sun,
Jianwu Dai
Publication year - 2019
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.9b01568
Subject(s) - chaff , microwave , materials science , x band , manganese , analytical chemistry (journal) , physics , metallurgy , chemistry , optoelectronics , chromatography , archaeology , quantum mechanics , history
A novel magnetic nanocomposite of Ni x Mn 1- x Fe 2 O 4 /carbonized chaff ( x = 0.3, 0.5, and 0.7) has been synthesized successfully via the co-carbonization and hydrothermal method. The microstructure, morphology, complex permittivity and permeability, and microwave absorbing properties were systematically studied by X-ray diffraction, scanning electron microscopy, and a vector network analyzer. Compared to the pure Ni 0.5 Mn 0.5 Fe 2 O 4 NPs, the Ni 0.3 Mn 0.7 Fe 2 O 4 /carbonized chaff-N 2 composite exhibits an optimal microwave absorption property at 4 mm as the mass percent of carbonized chaff is 10 wt %, the maximum reflection loss of which can reach -14.58 dB at 1.91 GHz with the -10 dB frequency bandwidth in the range of 1.46-2.41 GHz (0.95 GHz). The enhanced electromagnetic wave absorbing performance is ascribed to the good synergistic effect among laminated structures, better impedance matching condition, strong natural resonance loss, Debye dipolar relaxation to some extent, and so forth. Most importantly, this study provides a novel way to prepare easily degradable, environment-friendly, and high-efficiency electromagnetic wave absorbers by utilizing the structural property of renewable biomaterials.