Ligand-Rearrangement-Induced Transformation from a 3D Supramolecular Network to a Discrete Octanuclear Cluster: A Good Detector for Pb2+ and Cr2O72– | Zendy

Dandan Yang | Zendy; Yue Liu | Zendy; Shuangshuang Li | Zendy; Lin Cheng | Zendy; Ying Wang | Zendy; Ying-Xin Zhang | Zendy; Kai Chen | Zendy; Yixuan Gao | Zendy; Peng Ren | Zendy; Gregory S. Day | Zendy

Open Access

Ligand-Rearrangement-Induced Transformation from a 3D Supramolecular Network to a Discrete Octanuclear Cluster: A Good Detector for Pb²⁺ and Cr₂O₇^2–

Author(s) -

Dandan Yang,

Yue Liu,

Shuangshuang Li,

Lin Cheng,

Ying Wang,

Ying-Xin Zhang,

Kai Chen,

Yixuan Gao,

Peng Ren,

Gregory S. Day

Publication year - 2019

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.9b00680

Subject(s) - supramolecular chemistry , ligand (biochemistry) , cluster (spacecraft) , crystallography , chemistry , stereochemistry , crystal structure , receptor , computer science , biochemistry , programming language

A three-dimensional supramolecular framework containing both left- and right-handed helixes, {[Zn(TTPA)Cl 2 ]·1.63H 2 O} n ( 1 ), has been converted to a novel octanuclear cluster containing a metal-organic framework, [Zn 8 (ptptp) 6 Cl 2 ](ClO 4 ) 2 ·4CH 3 OH·2H 2 O ( 1b ), induced by ligand rearrangement during a solvothermal process. The luminescent properties of 1b indicate that the material can act as a selective probe toward Pb 2+ and Cr 2 O 7 2- .

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research