Imide-Based Polymers of Intrinsic Microporosity: Probing the Microstructure in Relation to CO2 Sorption Characteristics | Zendy

Worood A. ElMehalmey | Zendy; Rasha A. Azzam | Zendy; Youssef S. Hassan | Zendy; Mohamed H. Alkordi | Zendy; Tarek M. Madkour | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Imide-Based Polymers of Intrinsic Microporosity: Probing the Microstructure in Relation to CO₂ Sorption Characteristics

Author(s) -

Worood A. ElMehalmey,

Rasha A. Azzam,

Youssef S. Hassan,

Mohamed H. Alkordi,

Tarek M. Madkour

Publication year - 2018

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.7b02080

Subject(s) - microporous material , imide , sorption , polymer , materials science , microstructure , porosity , chemical engineering , polymer chemistry , organic chemistry , polymer science , chemistry , composite material , adsorption , engineering

A range of microporous, imide-based polymers were newly synthesized using two-step poly-condensation reactions of bis(carboxylic anhydride) and various aromatic diamines for CO 2 gas capture and storage applications. In this report, we attempted to assess the relative significance of molecular structural aspects through the manipulation of the conformational characteristics of the building blocks of the polymeric structures, the spiro-containing acid anhydride and the aromatic amines, to induce greater intrinsic microporosity and higher surface areas for the resulting solids. Results obtained from this study were thus used to outline a working relationship between the structural diversity of the constructed porous solids and their performance as CO 2 sorbents.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research