Open AccessCs-Symmetric Triphenylamine-Linked Bisthiazole-Based Metal-Free Donor–Acceptor Organic Dye for Efficient ZnO Nanoparticles-Based Dye-Sensitized Solar Cells: Synthesis, Theoretical Studies, and Photovoltaic Properties
Author(s) -
Ramesh Maragani,
Mohammad Shaad Ansari,
Avishek Banik,
Rajneesh Misra,
Mohammad Qureshi
Publication year - 2017
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.7b01100
Subject(s) - triphenylamine , photochemistry , materials science , dye sensitized solar cell , electron acceptor , electron donor , acceptor , energy conversion efficiency , photocurrent , dielectric spectroscopy , nanoparticle , moiety , chemistry , electrochemistry , optoelectronics , electrolyte , electrode , nanotechnology , organic chemistry , catalysis , physics , condensed matter physics
Herein, we have designed a metal-free donor-acceptor dye by incorporating an electron deficient bisthiazole moiety as a linker in between the electron donor triphenylamine and cyanoacetic acid acceptor. The bisthiazole-based organic dye D1 was synthesized using the Pd-catalyzed Suzuki cross-coupling and Knoevenagel condensation reactions. On the basis of the optical, electrochemical, and computational studies, dye D1 showed a better electronic interaction between the donor and acceptor moieties. As-synthesized C 2 symmetric triphenylamine-linked bisthiazole-based organic dye D1 has four anchoring groups, which play a significant role for better adsorption on the ZnO surface along with the enhanced kinetics of photoexcited electron injection. Consequently, photovoltaic properties of the organic dye D1 has been carried out by fabricating the ZnO nanoparticles (ZnO NPs)-based solar device. We obtained the maximum incident photon-to-current conversion efficiency of about 56.20%, with a short-circuit photocurrent density ( J sc ) of 13.60 mA cm -2 , which results in a power conversion efficiency (PCE) of 4.94% under AM 1.5 irradiation (100 mW cm -2 ). The high PCE value is the result of proficient electron injection from E LUMO of dye D1 to the conduction band of ZnO NPs, as suggested by the computational calculations. Electrochemical impedance spectroscopy measurement is carried out to calculate the electron lifetime and also reveals the insight to the reduced charge recombinations at the various active interfaces of the photovoltaic device.