Open AccessB(MIDA)-Containing Diborons
Author(s) -
Hiroto Yoshida,
Michinari Seki,
Ikuo Kageyuki,
Itaru Osaka,
Sayaka Hatano,
Manabu Abe
Publication year - 2017
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.7b01042
Subject(s) - chemistry , crystal structure , stereochemistry , crystallography
Unsymmetrical B(MIDA)-containing diborons of potential synthetic utility were found to be synthesized from the readily available (neop)B-B(neop) and (HO) 2 B-B(OH) 2 , and the procedure was extended to the generation of symmetrical (MIDA)B-B(MIDA). NMR and X-ray crystal structure studies revealed that B(MIDA) units of all of the diborons obtained in this study were in rigid tetrahedral environment.