Metal- and Solvent-Free Approach to Access 3-Se/S-Chromones from the Cyclization of Enaminones in the Presence of Dichalcogenides Catalyzed by KIO3 | Zendy

Jamal Rafique | Zendy; Sumbal Saba | Zendy; Alex Schneider | Zendy; Marcelo S. Franco | Zendy; Symara M. Silva | Zendy; Antônio L. Braga | Zendy

Open Access

Metal- and Solvent-Free Approach to Access 3-Se/S-Chromones from the Cyclization of Enaminones in the Presence of Dichalcogenides Catalyzed by KIO₃

Author(s) -

Jamal Rafique,

Sumbal Saba,

Alex Schneider,

Marcelo S. Franco,

Symara M. Silva,

Antônio L. Braga

Publication year - 2017

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.7b00445

Subject(s) - catalysis , chemistry , molar ratio , solvent , glycerol , combinatorial chemistry , organic chemistry

Herein, we describe a greener protocol for the one-pot synthesis of 3-Se/S-4 H -chromen-4-ones. The desired products were obtained in good to excellent yields using 2-hydroxyphenyl enaminones and half equivalents of various odorless diorganyl dichalcogenides (S/Se) in the presence of glycerol (5 molar equiv) and KIO 3 (15 mol %) as the catalyst under solvent-free conditions.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research