Open AccessStudy of Mercury [Hg(II)] Adsorption from Aqueous Solution on Functionalized Activated Carbon
Author(s) -
Oscar D. Caicedo Salcedo,
Diana Vargas,
Liliana Giraldo,
Juan Carlos Moreno–Piraján
Publication year - 2021
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.0c06084
Subject(s) - mercury (programming language) , adsorption , activated carbon , point of zero charge , chemistry , aqueous solution , titration , surface modification , sulfur , inorganic chemistry , nuclear chemistry , chemical engineering , organic chemistry , computer science , engineering , programming language
Mercury and its compounds are toxic substances, whose uncontrolled presence in the environment represents a danger to ecosystems and the organisms that inhabit in it. For this reason, in this work, we carried out a study of mercury [Hg(II)] adsorption from aqueous solution on functionalized activated carbon. The activated carbons were prepared by chemical activation of a mango seed with solutions of CaCl 2 and H 2 SO 4 at different concentrations, later, the carbonaceous materials were functionalized with Na 2 S, with the aim of increasing the sulfur content in the carbonaceous matrix and its affinity to mercury. The materials were characterized using: proximal analysis, scanning electron microscopy, Boehm titrations, point zero charge (pH PZC ), and infrared spectroscopy. Additionally, immersion calorimetries were performed in the mercury solution. The results of textural and chemical characterization show materials with low Brunauer-Emmett-Teller (BET) surface areas between 2 and 33 m 2 ·g -1 and low pore volumes. However, they had a rich surface chemistry of oxygenated groups. The enthalpies of immersion in the mercury solutions are between -31.71 and -77.31 J·g -1 , showing a correlation between the magnitude of the enthalpic data and the adsorption capacity of the materials. It was evidenced that the functionalization process produces a decrease in the surface area and pore volume of the activated carbons, and an increase in the sulfur content of the carbonaceous matrix. It was evidenced that the functionalization process generated an increase in the mercury [Hg(II)] adsorption capacity between 21 and 49% compared to those of the nonfunctionalized materials, reaching a maximum adsorption capacity of 85.6 mgHg 2+ g -1 .