Electrochemical Growth of Mg(OH)x Layered Films Stacked Parallel to the Substrates and Their Thermal Conversion to (111)-Oriented Nanoporous MgO Films | Zendy

Tsutomu Shinagawa | Zendy; Masaya Chigane | Zendy; Masanobu Izaki | Zendy

Open Access

Electrochemical Growth of Mg(OH)_x Layered Films Stacked Parallel to the Substrates and Their Thermal Conversion to (111)-Oriented Nanoporous MgO Films

Author(s) -

Tsutomu Shinagawa,

Masaya Chigane,

Masanobu Izaki

Publication year - 2021

Publication title -

acs omega

Language(s) - English

Resource type - Journals

ISSN - 2470-1343

DOI - 10.1021/acsomega.0c05619

Subject(s) - nanoporous , stacking , materials science , hydroxide , substrate (aquarium) , electrolysis , aqueous solution , magnesium , chemical engineering , electrochemistry , deposition (geology) , metal hydroxide , nanotechnology , chemistry , metallurgy , electrode , organic chemistry , electrolyte , geology , biology , engineering , paleontology , oceanography , sediment

Stacking layered metal hydroxide films parallel to a substrate is challenging. Here, we demonstrate a simple and rapid electrodeposition method for stacking magnesium hydroxide layered films. Room-temperature cathodic electrolysis (40 mA cm -2 ) in a Mg(NO 3 ) 2 aqueous solution induces the deposition of ⟨001⟩-oriented Mg(OH) x layered films stacked parallel to the substrate at the deposition rate of ∼2 μm min -1 . The obtained Mg(OH) x layered films undergo an overall oriented transformation by heat treatment to form ⟨111⟩-oriented nanoporous MgO films.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research