Coupling Analysis of Chemiluminescence and Pressure Changes in CH4/Air Explosion Suppressed by NaHCO3 Powder | Zendy

Liwei Cui | Zendy; Xiaobin Li | Zendy; Guang Yang | Zendy

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Coupling Analysis of Chemiluminescence and Pressure Changes in CH₄/Air Explosion Suppressed by NaHCO₃ Powder

Author(s) -

Liwei Cui,

Xiaobin Li,

Guang Yang

Publication year - 2020

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.0c02834

Subject(s) - chemiluminescence , coupling (piping) , high pressure , materials science , nuclear engineering , chemistry , physics , thermodynamics , metallurgy , engineering

This paper presents the coupling relationship between the flame emission spectrum and explosion characteristics of CH 4 /air mixtures with NaHCO 3 powder added. Due to the test of different concentrations of suppression powder in 20 L spherical-explosion-test devices, the flame emission spectrum and explosion pressure data were collected. In this experiment, four kinds of excited radicals, including CN*, HCHO*, CO*, and OH*, have a higher probability of being detected, and the changes of their existence duration and spectral intensity show strong regularity. Results reveal that for suppressant concentration in the range of 0-50 mg/L, together with the improvement of a suppression effect, the existence duration and spectral intensity of CN*, CO*, and OH* decrease, which is opposite to that of HCHO*. Besides, the spectral intensity of OH* and CO* shows a good linear relationship with the change of the maximum explosion pressure. Controlling the content of CN*, CO*, OH*, and HCHO* is of great significance in suppressing the explosion.

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