Electrochemical Synthesis of Sulfinate Esters: Nickel(II)-Catalyzed Oxidative Esterification of Thiols with Alcohols in an Undivided Cell | Zendy

Babak Kaboudin | Zendy; Leila Behrouzi | Zendy; Foad Kazemi | Zendy; Mohammad Mahdi Najafpour | Zendy; Hiroshi Aoyama | Zendy

Open Access

Electrochemical Synthesis of Sulfinate Esters: Nickel(II)-Catalyzed Oxidative Esterification of Thiols with Alcohols in an Undivided Cell

Author(s) -

Babak Kaboudin,

Leila Behrouzi,

Foad Kazemi,

Mohammad Mahdi Najafpour,

Hiroshi Aoyama

Publication year - 2020

Publication title -

acs omega

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.779

H-Index - 40

ISSN - 2470-1343

DOI - 10.1021/acsomega.0c00953

Subject(s) - nickel , electrochemistry , catalysis , chemistry , cyclic voltammetry , organic chemistry , oxidative phosphorylation , electrode , biochemistry

In this study, nickel-catalyzed electrochemical oxidative esterification of thiols with alcohols for the synthesis of sulfinate esters has been reported. The electrochemical oxidative esterification proceeded through a nickel-catalyzed oxidation of thiols using an undivided cell of graphite/nickel electrodes, where the nickel oxidation was studied by cyclic voltammetry. The method was conveniently and directly used for the one-pot synthesis of sulfinate esters of thiols.

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