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Experimental Kinetic Analysis of Potassium Extraction from Ultrapotassic Syenite Using NaCl–CaCl2 Salt Mixture
Author(s) -
Pegah Haseli,
Peter Majewski,
Farid Christo,
Mark Raven,
Steve Klose,
Frank Bruno
Publication year - 2020
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.0c00549
Subject(s) - potassium , salt (chemistry) , eutectic system , extraction (chemistry) , chemistry , inorganic chemistry , melting temperature , kinetic energy , mineralogy , materials science , chromatography , organic chemistry , microstructure , crystallography , physics , quantum mechanics , composite material
This kinetic experimental analysis reports on the application of a eutectic NaCl-CaCl 2 salt system for the extraction of potassium from ultrapotassic microsyenite. The reaction parameters, time, temperature, salt composition, and salt to ore ratio, were systematically analyzed. It was found that a salt mixture increases the potassium cation extraction in comparison with using either pure NaCl or pure CaCl 2 . It was also found that adding CaCl 2 into pure NaCl has a considerably stronger effect on increasing the potassium recovery than adding NaCl to pure CaCl 2 . The salt as a melting agent offers a reduction in the reaction temperature due to its lower melting temperature when compared to pure salts (NaCl or CaCl 2 ). Approximately 70% of K + in the deposit was extracted at 650 °C. Different characteristic methods have been used to understand the reaction mechanism of the salt mixture and ore, as well as to qualify and quantify the end product mineral phases.

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