Open AccessAdvanced Phosphorus Recovery from Municipal Wastewater using Anoxic/Aerobic Membrane Bioreactors and Magnesium Carbonate-Based Pellets
Author(s) -
Soryong Chae,
Brindha Murugesan,
Hyun-Sik Kim,
Dilip Kumar Duvvuru,
Tae Lee,
Yang-Hun Choi,
Mi-Hwa Baek,
Mallikarju. Nadagouda
Publication year - 2021
Publication title -
acs es and t water
Language(s) - English
Resource type - Journals
ISSN - 2690-0637
DOI - 10.1021/acsestwater.0c00300
Subject(s) - wastewater , pellets , phosphorus , anoxic waters , chemistry , eutrophication , suspended solids , pulp and paper industry , environmental chemistry , environmental engineering , nutrient , environmental science , materials science , organic chemistry , engineering , composite material
Effective recovery of phosphorus from municipal wastewater could be one of the best practical alternatives to protect aquatic environments from eutrophication and save natural phosphorus resources. This paper focuses on validating magnesium carbonate (MgCO 3 )-based pellets combined with a bench-scale anoxic/aerobic membrane bioreactor (MBR) system for advanced phosphorus recovery from municipal wastewater. As the flow rate of wastewater into the MgCO 3 column decreased from 10 L/d to 2.5 L/d, the phosphorus recovery rate of the MgCO 3 -based pellets increased from 54.3 to 93.5%. However, the column's severe clogging was found after a 13-days operation due to the high removal of total suspended solids (TSS) (~82%) through the MgCO 3 column. The anoxic/aerobic MBR introduction provided efficient removal of TSS, organic matter, and ammonia nitrogen before the MgCO 3 column. The combination of MBR with the MgCO 3 column achieved 73.1% phosphorus recovery from municipal wastewater without physical clogging. The P recovery capacity of the MgCO 3 -based pellets was maintained at 0.47 mg ortho-P/g MgCO 3 -based pellet during the continuous operation. Physical and chemical properties of MgCO 3 -based pellets before and after the experiment were characterized using scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), and Brunauer-Emmett-Teller (BET) surface area analyzer.