Open AccessCa2+ Ions Decrease Adhesion between Two (104) Calcite Surfaces as Probed by Atomic Force Microscopy
Author(s) -
Joanna Dziadkowiec,
Matea Ban,
Shaghayegh Javadi,
Bjørn Jamtveit,
Anja Røyne
Publication year - 2021
Publication title -
acs earth and space chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.876
H-Index - 19
ISSN - 2472-3452
DOI - 10.1021/acsearthspacechem.1c00220
Subject(s) - calcite , ionic bonding , ion , adhesion , chemistry , mineralogy , disjoining pressure , chemical engineering , materials science , nanotechnology , thin film , organic chemistry , engineering
Solution composition-sensitive disjoining pressure acting between the mineral surfaces in fluid-filled granular rocks and materials controls their cohesion, facilitates the transport of dissolved species, and may sustain volume-expanding reactions leading to fracturing or pore sealing. Although calcite is one of the most abundant minerals in the Earth's crust, there is still no complete understanding of how the most common inorganic ions affect the disjoining pressure (and thus the attractive or repulsive forces) operating between calcite surfaces. In this atomic force microscopy study, we measured adhesion acting between two cleaved (104) calcite surfaces in solutions containing low and high concentrations of Ca 2+ ions. We detected only low adhesion between calcite surfaces, which was weakly modulated by the varying Ca 2+ concentration. Our results show that the more hydrated calcium ions decrease the adhesion between calcite surfaces with respect to monovalent Na + at a given ionic strength, and thus Ca 2+ can sustain relatively thick water films between contacting calcite grains even at high overburden pressures. These findings suggest a possible loss of cohesion and continued progress of reaction-induced fracturing for weakly charged minerals in the presence of strongly hydrated ionic species.