Application of μ-Nitrido- and μ-Carbido-Bridged Iron Phthalocyanine Dimers as Cathode-Active Materials for Rechargeable Batteries | Zendy

Takeshi Shimizu | Zendy; Katsuhiro Wakamatsu | Zendy; Yasuyuki Yamada | Zendy; Yuka Toyoda | Zendy; Shigehisa Akine | Zendy; Kenji Yoza | Zendy; Hirofumi Yoshikawa | Zendy

Open Access

Application of μ-Nitrido- and μ-Carbido-Bridged Iron Phthalocyanine Dimers as Cathode-Active Materials for Rechargeable Batteries

Author(s) -

Takeshi Shimizu,

Katsuhiro Wakamatsu,

Yasuyuki Yamada,

Yuka Toyoda,

Shigehisa Akine,

Kenji Yoza,

Hirofumi Yoshikawa

Publication year - 2021

Publication title -

acs applied materials and interfaces

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.535

H-Index - 228

eISSN - 1944-8252

pISSN - 1944-8244

DOI - 10.1021/acsami.1c10540

Subject(s) - phthalocyanine , materials science , cyclic voltammetry , cathode , heteroatom , lithium (medication) , redox , electrode , inorganic chemistry , electrochemistry , nanotechnology , chemistry , metallurgy , organic chemistry , ring (chemistry) , medicine , endocrinology

μ-Nitrido- and μ-carbido-bridged iron phthalocyanine dimers, when used as cathode-active materials for rechargeable lithium batteries, showed four stable redox waves in cyclic voltammetry studies in solution and a stable discharge capacity of approximately 60 mAh g -1 after 200 cycles. These results indicate that μ-heteroatom-bridged iron phthalocyanine dimers are good platforms for designing novel phthalocyanine-based electrode-active materials.

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