Engaging Alkenyl Halides with Alkylsilicates via Photoredox Dual Catalysis | Zendy

Niki R. Patel | Zendy; Christopher B. Kelly | Zendy; Matthieu Jouffroy | Zendy; Gary A. Molander | Zendy

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Engaging Alkenyl Halides with Alkylsilicates via Photoredox Dual Catalysis

Author(s) -

Niki R. Patel,

Christopher B. Kelly,

Matthieu Jouffroy,

Gary A. Molander

Publication year - 2016

Publication title -

organic letters

Language(s) - Uncategorized

Resource type - Journals

SCImago Journal Rank - 1.94

H-Index - 239

eISSN - 1523-7060

pISSN - 1523-7052

DOI - 10.1021/acs.orglett.6b00024

Subject(s) - chemistry , halide , transmetalation , catalysis , alkyl , radical , dual role , nickel , photochemistry , primary (astronomy) , combinatorial chemistry , photoredox catalysis , organic chemistry , photocatalysis , physics , astronomy

Single-electron transmetalation via photoredox/nickel dual catalysis provides the opportunity for the construction of Csp(3)-Csp(2) bonds through the transfer of alkyl radicals under very mild reaction conditions. A general procedure for the cross-coupling of primary and secondary (bis-catecholato)alkylsilicates with alkenyl halides is presented. The developed method allows not only alkenyl bromides and iodides but also previously underexplored alkenyl chlorides to be employed.

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