Open AccessSynthesis of 1,1-Diboryl Alkenes Using the Boryl-Heck Reaction
Author(s) -
Olamide O. Idowu,
Jacob C. Hayes,
William B. Reid,
Donald A. Watson
Publication year - 2021
Publication title -
organic letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.94
H-Index - 239
eISSN - 1523-7060
pISSN - 1523-7052
DOI - 10.1021/acs.orglett.1c01567
Subject(s) - chemistry , regioselectivity , conjugated system , heck reaction , alkene , organic chemistry , combinatorial chemistry , catalysis , palladium , polymer
The synthesis of 1,1-diboryl alkenes from terminal alkenes is reported. 1,1-Regioselective addition is observed for both conjugated and unconjugated alkenes, allowing for a single method to prepare a wide range of 1,1-diboryl alkenes.