English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The synthesis, characterization, and catalytic activity of low-spin {CoNO} 8 pincer complexes of the type [Co(PCP)(NO)(H)] are described. These compounds are obtained either by reacting [Co(PCP)(κ 2 -BH 4 )] with NO and Et 3 N or, alternatively, by reacting [Co(PCP)(NO)] + with boranes, such as NH 3 ·BH 3 in solution. The five-coordinate, diamagnetic Co(III) complex [Co(PCP NMe - i Pr)(NO)(H)] was found to be the active species in the hydroboration of alkenes with anti-Markovnikov selectivity. A range of aromatic and aliphatic alkenes were efficiently converted with pinacolborane (HBpin) under mild conditions in good to excellent yield. Mechanistic insight into the catalytic reaction is provided by means of isotope labeling, NMR spectroscopy, and APCI/ESI-MS as well as DFT calculations.

Synthesis and Catalytic Reactivity of Cobalt Pincer Nitrosyl Hydride Complexes