Thin-Film Lubrication in the Water/Octyl β-d -Glucopyranoside System: Macroscopic and Nanoscopic Tribological Behavior
Author(s) -
Wei Chen,
Tobias Amann,
Andreas Kailer,
Jürgen Rühe
Publication year - 2019
Publication title -
langmuir
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.042
H-Index - 333
eISSN - 1520-5827
pISSN - 0743-7463
DOI - 10.1021/acs.langmuir.9b00383
Subject(s) - tribology , materials science , lubrication , nanoscopic scale , surface forces apparatus , viscosity , shear (geology) , shear rate , nanotribology , composite material , pulmonary surfactant , anisotropy , atomic force microscopy , nanotechnology , thermodynamics , optics , physics
The friction properties of the water-based surfactant system C8 (octyl β-d-glucopyranoside) are investigated both at the macro- and nanoscale in ring-on-plate and atomic force microscopy friction experiments, respectively. Surface characterization and measurement of the friction gap during sliding, together with the tribological behavior, show a strong shear rate dependence of the friction behavior. High shear rates of approximately 10 6 s -1 in the macroscopic friction experiments induce a molecular alignment of the surfactants in the friction gap. This generates an anisotropic viscosity which allows a high load to be carried but exhibits low viscosity in the shear direction. When the nanoscale and macroscale friction experiments are normalized to the same shear rate, almost identical frictional behavior is observed in the two regimes.
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