Organic Holmium(III) Complexes as a Potential Bright Emitter in Thin Films
Author(s) -
Chen Lyu,
Junjie Zhang,
Filippo S. Boi,
Huanqing Ye
Publication year - 2022
Publication title -
the journal of physical chemistry letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.563
H-Index - 203
ISSN - 1948-7185
DOI - 10.1021/acs.jpclett.2c02516
Subject(s) - photoluminescence , chromophore , thin film , materials science , excited state , ion , common emitter , energy transfer , holmium , optoelectronics , nanotechnology , photochemistry , optics , chemistry , chemical physics , laser , atomic physics , physics , organic chemistry
Holmium(III) ions incorporated with an organic ligand generate ∼2 μm optical emission which is characterized by steady and time-resolved photoluminescence. A potential efficient sensitization scheme is demonstrated by empirically calculating the Förster energy transfer rate and modeling the excited state dynamics of the ion. This is demonstrated by taking into account an ideal organic chromophore. The presented work proposes a promising material candidate for the 2 μm emission, which can be fabricated in thin films.
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