Open AccessStructural Characterization of a Novel Two-Dimensional Material: Cobalt Sulfide Sheets on Au(111)
Author(s) -
Mahesh K. Prabhu,
Dajo Boden,
Marcel J. Rost,
Jörg Meyer,
Irene M. N. Groot
Publication year - 2020
Publication title -
the journal of physical chemistry letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.563
H-Index - 203
ISSN - 1948-7185
DOI - 10.1021/acs.jpclett.0c02268
Subject(s) - cobalt , density functional theory , transition metal , sulfide , cobalt sulfide , materials science , substrate (aquarium) , characterization (materials science) , metal , character (mathematics) , chemical physics , crystallography , nanotechnology , computational chemistry , chemistry , metallurgy , geometry , organic chemistry , catalysis , oceanography , electrode , mathematics , electrochemistry , geology
Transition metal dichalcogenides (TMDCs) are a type of two-dimensional (2D) material that has been widely investigated by both experimentalists and theoreticians because of their unique properties. In the case of cobalt sulfide, density functional theory (DFT) calculations on free-standing S-Co-S sheets suggest there are no stable 2D cobalt sulfide polymorphs, whereas experimental observations clearly show TMDC-like structures on Au(111). In this study, we resolve this disagreement by using a combination of experimental techniques and DFT calculations, considering the substrate explicitly. We find a 2D CoS(0001)-like sheet on Au(111) that delivers excellent agreement between theory and experiment. Uniquely this sheet exhibits a metallic character, contrary to most TMDCs, and exists due to the stabilizing interactions with the Au(111) substrate.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom