Chemical Shielding Anisotropies for Chloroform Exchanging between a Free Site and a Complex with Cryptophane-D: A Cross-Correlated NMR Relaxation Study | Zendy

Emilie Steiner | Zendy; Thierry Brotin | Zendy; Zoltán Takács | Zendy; Józef Kowalewski | Zendy

Open Access

Chemical Shielding Anisotropies for Chloroform Exchanging between a Free Site and a Complex with Cryptophane-D: A Cross-Correlated NMR Relaxation Study

Author(s) -

Emilie Steiner,

Thierry Brotin,

Zoltán Takács,

Józef Kowalewski

Publication year - 2015

Publication title -

the journal of physical chemistry b

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.864

H-Index - 392

eISSN - 1520-6106

pISSN - 1520-5207

DOI - 10.1021/acs.jpcb.5b05218

Subject(s) - anisotropy , chemistry , electromagnetic shielding , spins , relaxation (psychology) , dipole , molecular physics , polarization (electrochemistry) , molecule , chemical shift , isotropy , nuclear magnetic resonance , analytical chemistry (journal) , condensed matter physics , materials science , physics , optics , psychology , social psychology , organic chemistry , chromatography , composite material

The case of (13)C-labeled chloroform exchanging between a free site in solution and the encaged site within the cryptophane-D cavity is investigated using the measurements of longitudinal cross-correlated relaxation rates, involving the interference of the dipole-dipole and chemical shielding anisotropy interactions. A compact theoretical expression is provided, along with an experimental protocol, based on INEPT (insensitive nuclei enhanced by polarization)-enhanced double-quantum-filtered inversion recovery measurements. The analysis of the build-up curves results in a set of cross-correlated relaxation rates for both the (13)C and (1)H spins at the two sites. It is demonstrated that the results can be given a consistent interpretation in terms of molecular-level properties, such as rotational correlation times, the Lipari-Szabo order parameter, and interaction strength constants. The analysis yields the bound-site carbon-13 chemical shielding anisotropy, ΔσC = -58 ± 8 ppm, in good agreement with most recent liquid-crystal measurements and the corresponding proton shielding anisotropy, ΔσH = 14 ± 2 ppm.

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