The H•/H– Redox Couple and Absolute Hydration Energy of H–

A supermolecule-continuum approach with water clusters up to n = 16 H 2 O molecules has been used to predict the absolute hydration free energies at 298 K (Δ G hyd ) of both hydrogen (H•) and hydride (H - ) to be 4.6 ± 1 and -78 ± 3 kcal/mol, respectively. These values are combined with a high accuracy prediction of the gas-phase electron affinity (Δ G gas,298K = -16.9 kcal/mol) to determine the aqueous electron affinity of H• of 99.5 ± 3 kcal/mol, which yields a reduction potential for H• vs SHE of -0.03 ± 0.15 V. This value is in agreement within 0.2 V with most estimates obtained using a wide variety of approaches. These results can be used to improve the absolute hydricity scale in water which provides additional insights into how a putative hydride interacts with solvent but do not change the ability to predict the relative reactivity of two species using relative hydricity scales.