Photoredox-Catalyzed Hydrosulfonylation of Arylallenes | Zendy

Olga А. Storozhenko | Zendy; Alexey А. Festa | Zendy; Galina I. Detistova | Zendy; Victor B. Rybakov | Zendy; А. В. Варламов | Zendy; Erik V. Van der Eycken | Zendy; Leonid G. Voskressensky | Zendy

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Photoredox-Catalyzed Hydrosulfonylation of Arylallenes

Author(s) -

Olga А. Storozhenko,

Alexey А. Festa,

Galina I. Detistova,

Victor B. Rybakov,

А. В. Варламов,

Erik V. Van der Eycken,

Leonid G. Voskressensky

Publication year - 2019

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.2

H-Index - 228

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/acs.joc.9b02960

Subject(s) - sulfonyl , catalysis , photoredox catalysis , eosin y , chemistry , photocatalysis , sodium , reaction conditions , organic chemistry , alkyl

(Het)Arylallenes undergo hydrosulfonylation under photoredox-catalyzed conditions. The reaction gives vinyl sulfones in a regio- and diastereoselective manner, employing sodium sulfinates as the sulfonyl source and eosin Y as the photocatalyst. Indol-1-yl, pyrrol-1-yl, phenyl, and naphtylallenes might be used. Aliphatic allenes are incompatible with the reaction conditions.

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