Introduction of Aryl Fluorosulfates into the Realm of Catellani Reaction Substrates | Zendy

Vidmantas Bieliūnas | Zendy; Wim M. De Borggraeve | Zendy

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Introduction of Aryl Fluorosulfates into the Realm of Catellani Reaction Substrates

Author(s) -

Vidmantas Bieliūnas,

Wim M. De Borggraeve

Publication year - 2019

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.2

H-Index - 228

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/acs.joc.9b02352

Subject(s) - aryl , alkylation , combinatorial chemistry , halide , phenol , complementarity (molecular biology) , chemistry , computer science , organic chemistry , catalysis , biology , alkyl , genetics

Application of activated phenol fluorosulfates as substrates in a Pd/NBE mediated sequential alkylation-arylation, commonly known as a Catellani reaction, is presented. These substrates provide a level of complementarity to the commonly used aryl halides and, in combination with a plethora of existing Catellani reaction variations, enable even wider application of this powerful synthetic tool.

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