Unexpected Formation of Hexasubstituted Arenes through a 2-fold Palladium-Mediated Ligand Arylation | Zendy

Corin Wagen | Zendy; Bryan T. Ingoglia | Zendy; Stephen L. Buchwald | Zendy

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Unexpected Formation of Hexasubstituted Arenes through a 2-fold Palladium-Mediated Ligand Arylation

Author(s) -

Corin Wagen,

Bryan T. Ingoglia,

Stephen L. Buchwald

Publication year - 2019

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.2

H-Index - 228

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/acs.joc.9b02091

Subject(s) - chemistry , palladium , stereochemistry , ligand (biochemistry) , molecule , x ray crystallography , medicinal chemistry , catalysis , organic chemistry , receptor , diffraction , biochemistry , physics , optics

A rearrangement reaction of biarylphosphine-supported Pd(II) complexes was employed to synthesize 1,3,5-triaryl 2,4,6-triisopropylbenzene compounds, a class of molecules that has not previously been reported. The strain of the central hexasubstituted ring was investigated via X-ray crystallography.

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