Spiro-BODIPYs with a Diaryl Chelate: Impact on Aggregation and Luminescence | Zendy

Kang Yuan | Zendy; Xiang Wang | Zendy; Soren K. Mellerup | Zendy; Igor Kozin | Zendy; Suning Wang | Zendy

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Spiro-BODIPYs with a Diaryl Chelate: Impact on Aggregation and Luminescence

Author(s) -

Kang Yuan,

Xiang Wang,

Soren K. Mellerup,

Igor Kozin,

Suning Wang

Publication year - 2017

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.2

H-Index - 228

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/acs.joc.7b02602

Subject(s) - luminescence , chelation , aggregation induced emission , chemistry , photochemistry , materials science , optoelectronics , inorganic chemistry , fluorescence , physics , optics

Spiro-BODIPYs with a diaryl chelate unit have been found to form J-aggregates in methanol-water solvent mixture and brightly emissive in the solid state. The diaryl chelate unit has a significant impact on J-aggregates and fluorescence of BODIPYs. Crystal structural analysis reveals that the spiro-structures facilitate J-stacking in the solid state.

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