One-Pot Synthesis of Unsymmetric Diaryliodonium Salts from Iodine and Arenes | Zendy

Erik Lindstedt | Zendy; Marcus Reitti | Zendy; Berit Olofsson | Zendy

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One-Pot Synthesis of Unsymmetric Diaryliodonium Salts from Iodine and Arenes

Author(s) -

Erik Lindstedt,

Marcus Reitti,

Berit Olofsson

Publication year - 2017

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.2

H-Index - 228

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/acs.joc.7b01652

Subject(s) - chemistry , moiety , reagent , iodine , iodine compounds , combinatorial chemistry , organic chemistry

The first synthesis of unsymmetric diaryliodonium salts directly from iodine and arenes is presented. The methodology provides diaryliodonium salts with the trimethoxyphenyl (TMP) moiety as dummy group. The protocol avoids the customary use of iodoarenes, which can be both expensive and toxic. Excess reagents are not required, and the reactions are performed under mild conditions. O-Arylations with these TMP salts were demonstrated to be highly chemoselective.

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