Phenol Derivatives as Coupling Partners with Alkylsilicates in Photoredox/Nickel Dual Catalysis | Zendy

Niki R. Patel | Zendy; Gary A. Molander | Zendy

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Phenol Derivatives as Coupling Partners with Alkylsilicates in Photoredox/Nickel Dual Catalysis

Author(s) -

Niki R. Patel,

Gary A. Molander

Publication year - 2016

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.2

H-Index - 228

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/acs.joc.6b00800

Subject(s) - chemistry , nickel , phenol , catalysis , dual (grammatical number) , coupling (piping) , photochemistry , photoredox catalysis , organic chemistry , combinatorial chemistry , photocatalysis , metallurgy , art , materials science , literature

Photoredox/nickel dual catalysis via single electron transmetalation allows coupling of Csp(3)-Csp(2) hybridized centers under mild conditions. A procedure for the coupling of electron-deficient aryl triflates, -tosylates, and -mesylates with alkylbis(catecholato)silicates is presented. This method represents the first example of the use of phenol derivatives as electrophilic coupling partners in photoredox/nickel dual catalysis.

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