Synthesis and Transport Studies of a Cofacial Porphyrin Cyclophane | Zendy

Patrick Zwick | Zendy; Chunwei Hsu | Zendy; Maria El Abbassi | Zendy; Olaf Fuhr | Zendy; Dieter Fenske | Zendy; Diana Dulić | Zendy; Herre S. J. van der Zant | Zendy; Marcel Mayor | Zendy

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Synthesis and Transport Studies of a Cofacial Porphyrin Cyclophane

Author(s) -

Patrick Zwick,

Chunwei Hsu,

Maria El Abbassi,

Olaf Fuhr,

Dieter Fenske,

Diana Dulić,

Herre S. J. van der Zant,

Marcel Mayor

Publication year - 2020

Publication title -

the journal of organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.2

H-Index - 228

eISSN - 1520-6904

pISSN - 0022-3263

DOI - 10.1021/acs.joc.0c01957

Subject(s) - cyclophane , porphyrin , chemistry , mechanosensitive channels , molecule , calixarene , polycyclic compound , crystallography , stereochemistry , photochemistry , organic chemistry , ion channel , biochemistry , receptor

Porphyrin cyclophane 1 , consisting of two rigidly fixed but still movable cofacial porphyrins and exposing acetate-masked thiols in opposed directions of the macrocycle, is designed, synthesized, and characterized. The functional cyclophane 1 , as pioneer of mechanosensitive 3D materials, forms stable single-molecule junctions in a mechanically controlled break-junction setup. Its reliable integration in a single-molecule junction is a fundamental prerequisite to explore the potential of these structures as mechanically triggered functional units and devices.

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