Structural, Electronic, and Thermal Properties of CdSnAs2
Author(s) -
Wilarachchige D. C. B. Gunatilleke,
Dean Hobbis,
Hagen Poddig,
Austin Tinkess,
Matt Beekman,
Hsin Wang,
Kaya Wei,
Ryan Baumbach,
George S. Nolas
Publication year - 2020
Publication title -
inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 233
eISSN - 1520-510X
pISSN - 0020-1669
DOI - 10.1021/acs.inorgchem.9b03424
Subject(s) - chemistry , debye model , atmospheric temperature range , crystallite , microcrystalline , thermal , thermal conductivity , work (physics) , homogeneous , phase (matter) , range (aeronautics) , thermodynamics , chemical physics , composite material , crystallography , materials science , physics , organic chemistry
Structural, electrical, and thermal properties of CdSnAs 2 , with analyses from temperature-dependent transport properties over a large temperature range, are reported. Phase-pure microcrystalline powders were synthesized that were subsequently densified to a high-density homogeneous polycrystalline specimen for this study. Temperature-dependent transport indicates n -type semiconducting behavior with a very high and nearly temperature independent mobility over the entire measured temperature range, attributed to the very small electron effective mass of this material. The Debye model was successfully applied to model the thermal conductivity and specific heat. This work contributes to the fundamental understanding of this material, providing further insight and allowing for investigations into altering this and related physical properties of these materials for technological applications.
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