Structure and Phase Transformation in the Giant Magnetostriction Laves-Phase SmFe2

As one class of the most important intermetallic compounds, the binary Laves-phase is well-known for its abundant magnetic properties. Samarium-iron alloy system SmFe 2 is a prototypical Laves compound that shows strong negative magnetostriction but relatively weak magnetocrystalline anisotropy. SmFe 2 has been identified as a cubic Fd3̅m structure at room temperature; however, the cubic symmetry, in principle, does not match the spontaneous magnetization along the [111] cubic direction. Here we studied the crystal structure of SmFe 2 by high-resolution synchrotron X-ray powder diffraction, X-ray total scattering, and selected-area electron diffraction methods. SmFe 2 is found to adopt a centrosymmetric trigonal R3̅m structure at room temperature, which transforms to an orthorhombic Imma structure at 200 K. This transition is in agreement with the changes of easy magnetization direction from [111] cubic o [110] cubic direction and is further evidenced by the inflection of thermal expansion behavior, the sharp decline of the magnetic susceptibility in the field-cooling-zero field-cooling curve, and the anomaly in the specific heat capacity measurement. The revised structure and phase transformation of SmFe 2 could be useful to understand the magnetostriction and related physical properties of other RM 2 -type pseudocubic Laves-phase intermetallic compounds.