One-Pot Hydrothermal Synthesis of TbIII13(GeO4)6O7(OH) and K2TbIVGe2O7: Preparation of a Stable Terbium(4+) Complex | Zendy

Kyle Fulle | Zendy; Liurukara D. Sanjeewa | Zendy; Colin D. McMillen | Zendy; Yimei Wen | Zendy; Apeksha C. Rajamanthrilage | Zendy; Jeffrey N. Anker | Zendy; George Chumanov | Zendy; Joseph W. Kolis | Zendy

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One-Pot Hydrothermal Synthesis of Tb^III₁₃(GeO₄)₆O₇(OH) and K₂Tb^IVGe₂O₇: Preparation of a Stable Terbium(4+) Complex

Author(s) -

Kyle Fulle,

Liurukara D. Sanjeewa,

Colin D. McMillen,

Yimei Wen,

Apeksha C. Rajamanthrilage,

Jeffrey N. Anker,

George Chumanov,

Joseph W. Kolis

Publication year - 2017

Publication title -

inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 233

eISSN - 1520-510X

pISSN - 0020-1669

DOI - 10.1021/acs.inorgchem.7b00821

Subject(s) - terbium , isostructural , chemistry , hydrothermal circulation , crystallography , polyhedron , hydrothermal synthesis , oxide , solid state , oxidation state , inorganic chemistry , crystal structure , metal , chemical engineering , ion , combinatorics , mathematics , organic chemistry , engineering

Two terbium germanates have been synthesized via high-temperature and high-pressure hydrothermal synthesis with 20 M KOH as a mineralizer using Tb 4 O 7 as a starting material. Tb 13 (GeO 4 ) 6 O 7 (OH) crystallizes in trigonal space group R3̅, is built up of isolated GeO 4 units, and contains a complex arrangement of terbium oxide polyhedra. K 2 TbGe 2 O 7 is a terbium(4+) pyrogermanate that is isostructural with K 2 ZrGe 2 O 7 and displays a rare stable Tb 4+ oxidation state in the solid state.

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