Holmium(III) Single-Ion Magnet for Cryomagnetic Refrigeration Based on an MRI Contrast Agent Derivative | Zendy

Borja Rodríguez-Barea | Zendy; Júlia Mayans | Zendy; Renato Rabelo | Zendy; Adrián Sanchis-Perucho | Zendy; Nicolás Moliner | Zendy; José MartínezLillo | Zendy; Miguel Julve | Zendy; Francesc Lloret | Zendy; Rafael RuizGarcía | Zendy; Joan Cano | Zendy

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Holmium(III) Single-Ion Magnet for Cryomagnetic Refrigeration Based on an MRI Contrast Agent Derivative

Author(s) -

Borja Rodríguez-Barea,

Júlia Mayans,

Renato Rabelo,

Adrián Sanchis-Perucho,

Nicolás Moliner,

José MartínezLillo,

Miguel Julve,

Francesc Lloret,

Rafael RuizGarcía,

Joan Cano

Publication year - 2021

Publication title -

inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 233

eISSN - 1520-510X

pISSN - 0020-1669

DOI - 10.1021/acs.inorgchem.1c01905

Subject(s) - magnetic refrigeration , chemistry , gadolinium , holmium , magnetization , contrast (vision) , magnet , nuclear magnetic resonance , derivative (finance) , crystallography , magnetic field , organic chemistry , laser , physics , quantum mechanics , financial economics , optics , economics , artificial intelligence , computer science

The coexistence of field-induced blockage of the magnetization and significant magnetocaloric effects in the low-temperature region occurs in a mononuclear holmium(III) diethylenetriamine- N , N , N ', N ″, N ″-pentaacetate complex, whose gadolinium(III) analogue is a commercial MRI contrast agent. Both properties make it a suitable candidate for cryogenic magnetic refrigeration, thus enlarging the variety of applications of this simple class of multifunctional molecular nanomagnets.

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