A Second Modification of Beryllium Bromide: β-BeBr2 | Zendy

Magnus R. Buchner | Zendy; Fabian Dankert | Zendy; Nils Spang | Zendy; Florian Pielnhofer | Zendy; Carsten von Hänisch | Zendy

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A Second Modification of Beryllium Bromide: β-BeBr₂

Author(s) -

Magnus R. Buchner,

Fabian Dankert,

Nils Spang,

Florian Pielnhofer,

Carsten von Hänisch

Publication year - 2020

Publication title -

inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 233

eISSN - 1520-510X

pISSN - 0020-1669

DOI - 10.1021/acs.inorgchem.0c02832

Subject(s) - chemistry , beryllium , bromide , recrystallization (geology) , iodide , raman spectroscopy , benzene , crystallography , crystal structure , inorganic chemistry , organic chemistry , optics , paleontology , physics , biology

The synthesis of a second beryllium bromide modification, β-BeBr 2 , was accomplished through recrystallization of α-BeBr 2 from benzene in the presence of cyclo -decamethylpentasiloxane. This phase was analyzed via single-crystal X-ray diffraction and IR and Raman spectroscopy as well as density functional theory calculations. This enabled a comparison to α-BeBr 2 and the α and β phases of beryllium chloride and iodide.

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