Open AccessStability of a Benzyl Amine Based CO2 Capture Adsorbent in View of Regeneration Strategies
Author(s) -
Qian Yu,
Jorge de la P. Delgado,
Rens Veneman,
Wim Brilman
Publication year - 2017
Publication title -
industrial and engineering chemistry research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.878
H-Index - 221
eISSN - 1520-5045
pISSN - 0888-5885
DOI - 10.1021/acs.iecr.6b04645
Subject(s) - thermogravimetric analysis , adsorption , sorbent , amine gas treating , chemistry , thermal stability , fourier transform infrared spectroscopy , stripping (fiber) , degradation (telecommunications) , nitrogen , chemical engineering , ion exchange , elemental analysis , materials science , inorganic chemistry , organic chemistry , ion , telecommunications , computer science , engineering , composite material
In this work, the chemical and thermal stability of a primary amine-functionalized ion-exchange resin (Lewatit VP OC 1065) is studied in view of the potential options of regenerating this sorbent in a CO 2 removal application. The adsorbent was treated continuously in the presence of air, different O 2 /CO 2 /N 2 mixtures, concentrated CO 2 , and steam, and then the remaining CO 2 adsorption capacity was measured. Elemental analysis, BET/BJH analysis, Fourier transform infrared spectroscopy, and thermogravimetric analysis were applied to characterize adsorbent properties. This material was found to be thermally and hydrothermally stable at high temperatures. However, significant oxidative degradation occurred already at moderate temperatures (above 70 °C). Temperatures above 120 °C lead to degradation in concentrated dry CO 2 . Adding moisture to the concentrated CO 2 stream improves the CO 2 -induced stability. Adsorbent regeneration with nitrogen stripping is studied with various parameters, focusing on minimizing the moles of purge gas required per mole of CO 2 desorbed.