Open AccessPhase Behavior of Hydrocarbon-like Primary Organic Aerosol and Secondary Organic Aerosol Proxies Based on Their Elemental Oxygen-to-Carbon Ratio
Author(s) -
Fabian Mahrt,
Elli Newman,
Yuanzhou Huang,
Markus Ammann,
Allan K. Bertram
Publication year - 2021
Publication title -
environmental science and technology
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.851
H-Index - 397
eISSN - 1520-5851
pISSN - 0013-936X
DOI - 10.1021/acs.est.1c02697
Subject(s) - aerosol , environmental chemistry , hydrocarbon , chemistry , total organic carbon , phase (matter) , carbon fibers , mass fraction , fraction (chemistry) , relative humidity , materials science , organic chemistry , meteorology , physics , composite number , composite material
A large fraction of atmospheric aerosols can be characterized as primary organic aerosol (POA) and secondary organic aerosol (SOA). Knowledge of the phase behavior, that is, the number and type of phases within internal POA + SOA mixtures, is crucial to predict their effect on climate and air quality. For example, if POA and SOA form a single phase, POA will enhance the formation of SOA by providing organic mass to absorb SOA precursors. Using microscopy, we studied the phase behavior of mixtures of SOA proxies and hydrocarbon-like POA proxies at relative humidity (RH) values of 90%, 45%, and below 5%. Internal mixtures of POA and SOA almost always formed two phases if the elemental oxygen-to-carbon ratio (O/C) of the POA was less than 0.11, which encompasses a large fraction of atmospheric hydrocarbon-like POA from fossil fuel combustion. SOA proxies mixed with POA proxies having 0.11 ≤ O/C ≤ 0.29 mostly resulted in particles with one liquid phase. However, two liquid phases were also observed, depending on the type of SOA and POA surrogates, and an increase in phase-separated particles was observed when increasing the RH in this O/C range. The results have implications for predicting atmospheric SOA formation and policy strategies to reduce SOA in urban environments.