Catalytic Applications of Vanadium: A Mechanistic Perspective | Zendy

Ryan R. Langeslay | Zendy; David M. Kaphan | Zendy; Christopher L. Marshall | Zendy; Peter C. Stair | Zendy; Alfred P. Sattelberger | Zendy; Massimiliano Delferro | Zendy

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Catalytic Applications of Vanadium: A Mechanistic Perspective

Author(s) -

Ryan R. Langeslay,

David M. Kaphan,

Christopher L. Marshall,

Peter C. Stair,

Alfred P. Sattelberger,

Massimiliano Delferro

Publication year - 2018

Publication title -

chemical reviews

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 20.528

H-Index - 700

eISSN - 1520-6890

pISSN - 0009-2665

DOI - 10.1021/acs.chemrev.8b00245

Subject(s) - chemistry , vanadium , catalysis , combinatorial chemistry , perspective (graphical) , nanotechnology , organic chemistry , materials science , artificial intelligence , computer science

The chemistry of vanadium has seen remarkable activity in the past 50 years. In the present review, reactions catalyzed by homogeneous and supported vanadium complexes from 2008 to 2018 are summarized and discussed. Particular attention is given to mechanistic and kinetics studies of vanadium-catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species, as well as oxidative C-C and C-O bond cleavage, carbon-carbon bond formation, deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis polymerization, and oxo/imido heterometathesis. Additionally, insights into heterogeneous vanadium catalysis are provided when parallels can be drawn from the homogeneous literature.

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