Cooperative 1D Triazole-Based Spin Crossover FeII Material With Exceptional Mechanical Resilience | Zendy

Narsimhulu Pittala | Zendy; Franck Thétiot | Zendy; Smaı̈l Triki | Zendy; Kamel Boukheddaden | Zendy; Guillaume Chastanet | Zendy; Mathieu Marchivie | Zendy

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Cooperative 1D Triazole-Based Spin Crossover Fe^II Material With Exceptional Mechanical Resilience

Author(s) -

Narsimhulu Pittala,

Franck Thétiot,

Smaı̈l Triki,

Kamel Boukheddaden,

Guillaume Chastanet,

Mathieu Marchivie

Publication year - 2016

Publication title -

chemistry of materials

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 3.741

H-Index - 375

eISSN - 1520-5002

pISSN - 0897-4756

DOI - 10.1021/acs.chemmater.6b04118

Subject(s) - resilience (materials science) , spin crossover , crossover , materials science , spin (aerodynamics) , nanotechnology , physics , radiochemistry , chemistry , computer science , condensed matter physics , engineering , composite material , mechanical engineering , artificial intelligence

International audienceThe magnetic spin change associated with the spin crossover (SCO) phenomenon represents a paradigm of bistability at the molecular level that is of current interest because of potential applications in the development of new generations of electronic devices such as nonvolatil memories, molecular sensors and displays.(1-5) The SCO phenomenon is especially observed in FeII complexes in which the paramagnetic high spin state (HS, S = 2) can be switched reversibly to the low spin state (LS, S = 0) by several external stimuli such as temperature, pressure or light irradiation.(6) A huge effort has been devoted to the understanding of the transition mechanisms using inter alia crystallographic tools..

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