Open AccessScaling the Analytical Information Given by Several Types of Colorimetric and Spectroscopic Instruments Including Smartphones: Rules for Their Use and Establishing Figures of Merit of Solid Chemosensors
Author(s) -
Adrià MartínezAviñó,
C. MolinsLegua,
P. Campı́ns-Falcó
Publication year - 2021
Publication title -
analytical chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.117
H-Index - 332
eISSN - 1520-6882
pISSN - 0003-2700
DOI - 10.1021/acs.analchem.0c03994
Subject(s) - chemistry , detection limit , figure of merit , instrumentation (computer programming) , point (geometry) , process engineering , rgb color model , hydrogen sulfide , footprint , limit (mathematics) , analytical chemistry (journal) , chromatography , computer science , artificial intelligence , computer vision , mathematics , engineering , paleontology , sulfur , geometry , organic chemistry , biology , operating system , mathematical analysis
The analytical information given by different types of instruments was scaled in order to establish suitably the figures of merit of a given methodology based on color measurements. Different lab and portable instruments, including smartphones with and without a miniaturized spectrophotometer accessory, have been tested. In order to obtain broad information and using objective criteria, these instruments have been compared from (1) the analytical point of view, considering mainly the detection limit (limits of detection [LODs]), selectivity, accuracy and intra- and interday precision, size, components, and costs; and (2) the environmental point of view, based on their footprint as kilograms of CO 2 . No significant differences in the precision were obtained with RSD (%) values lower than 10% for all of the instruments, but the achieved values of LOD, selectivity, accuracy, and cost were different. Footprints of CO 2 were better for portable instrumentation, especially for smartphones. Three solid chemosensors made of different materials (PDMS, paper, or nylon) have been tested for the determination of ammonia and hydrogen sulfide at different concentration levels (ppb levels). As a result of this study, some rules for selecting the instrument for obtaining the required information have been established. Two apps have been developed for quantitation by smartphones, one for working with RGB values and the other for spectra obtained by the miniaturized spectrophotometer coupled to a smartphone.