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Synthesis of modified ZnO nanorods and investigation of its application for removal of phthalate from landfill leachate: A case study in Aradkouh landfill site
Author(s) -
Akbar Eslami,
Mohammad Hossien Saghi,
Behrouz Akbariadergani,
Shahram Sadeghi,
Mansour Ghaderpoori,
Mahboubeh Rabbani,
Abdolazim Alinejad
Publication year - 2021
Publication title -
journal of environmental health science and engineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.447
H-Index - 45
ISSN - 2052-336X
DOI - 10.1007/s40201-020-00587-5
Subject(s) - nanorod , x ray photoelectron spectroscopy , leachate , scanning electron microscope , materials science , dynamic light scattering , zinc , transmission electron microscopy , nuclear chemistry , chemical engineering , nanoparticle , chemistry , environmental chemistry , nanotechnology , metallurgy , composite material , engineering
In this study, zinc oxide nanorods, co-doped with iron and silver, were synthesized in a co-precipitation method. Its properties were determined using X-ray diffraction (XRD), Transmission electron microscopy (TEM), Field Emission Scanning Electron Microscopy (FE-SEM), Brunauer-Emmett-Teller (BET), Dynamic light scattering (DLS) and X-ray photoelectron spectroscopy (XPS) analysis. The results of FE-SEM and TEM showed that zinc oxide nanoparticles synthesized and co-doped with iron and silver were formed as separate nanorods. Also, the average values of DBP and DEHP amount of phthalates in the leachate from the landfill site of Aradkouh were obtained 52.5 and 94.69 mg/L, respectively. The highest removal efficiency in real samples for phthalates was found to be 52%. The highest removal efficiency of TOC were was 61%. The synthesized nanostructure could have proper efficiency in removal of phthalates from water sources under the visible light of LED lamp.

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